Ni-catalyzed asymmetric reductive allylation of aldehydes with allylic carbonates.
نویسندگان
چکیده
This work features first asymmetric Ni-catalyzed reductive coupling of allylic carbonates with aldehydes, which may proceed via allyl-Ni intermediates although Zn was used as the terminal reductant. Moderate to excellent enantiomeric excess was obtained with excellent functional group tolerance.
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ورودعنوان ژورنال:
- Chemical communications
دوره 50 29 شماره
صفحات -
تاریخ انتشار 2014